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Chemistries

If you go to an electronic store, there are plenty of batteries to choose from. The following is a table describing the different types of batteries and their characteristics.


Table 4.1: Battery Chemistry Comparison
Chemistry Strength Weakness
Alkaline Alkaline batteries are popular for small electronic devices and toys. These batteries have a high energy density and they are usually quite inexpensive when you guy ``store brands''. Alkaline batteries have high internal resistance. This means even though they have a high energy-density, it is not possible to release energy at a fast rate. Furthermore, alkaline batteries discharge at a linear slope. This means the output voltage continues to drop linearly as the battery discharges. This characteristics affect the torque or motors severely. Most alkaline batteries are not designed to be rechargeable, making the long-run rather expensive.
NiCd Nickel Cadium batteries represent the majority of rechargeable batteries. The internal resistance of NiCd batteries is small, making these batteries dangerously efficient at fast discharging. NiCd batteries can be trickle charged, which means a recharger can be inexpensively made. Being rechargeable, NiCd batteries are economical in the long run. NiCd batteries have memory effect. This means when a battery is recharged without first completely discharged, the capacity of the battery will be limited. Furthermore, NiCd batteries have a relatively low energy-density. This means it takes more mass to store the same aount of energy compared to high energy-density batteries.
NiMH Nickel Metal Hydride batteries share many advantages with NiCd batteries. In addition, NiMH batteries have twice the energy-density of NiCd batteries. For the same size and same mass, a NiMH battery stores twice the amount of energy. NiMH batteries also have low internal resistance and are rechargeable. NiMH batteries do not have memory effect, which means they do not need to be empty before being recharged. Unlike NiCd batteries, NiMH batteries cannot be trickle charged. This is a minor issue because it is still easy to correctly charge NiMH batteries with a constant current source and a voltage monitor.
Li-ion Lithium-ion batteries are used in many high-end cordless and rechargeable devices. The energy-density of Lithium-ion batteries is higher than that of NiMH batteries. Although Li-ion batteries seem very suitable for robotics, they have some limitations. Li-ion batteries are not designed for continuous high drain rate. This is why cordless power tools do not use Li-ion batteries. It is also quite difficult to charge Li-ion batteries with home made circuits. Li-ion batteries require constant current charging for the first stage, then constant voltage should take over for the second stage.



next up previous contents
Next: Voltage Regulation Up: Energy System Previous: Energy System   Contents
Tak Auyeung 2003-09-29